又因为 $f\left(\frac{1}{3 k}-1\right)>f(0)=0, f\left(\frac{1}{2 k}\right)=\ln \left(1+\frac{1}{2 k}\right)-\frac{1}{2 k}<0$ ,
所以 $\exists x_{2} \in\left(\frac{1}{3 k}-1, \frac{1}{2 k}\right), f\left(x_{2}\right)=0$ ,
即 $x_{2}$ 是 $f(x)$ 在 $(0,+\infty)$ 上唯一的零点;
②解:(i)因为 $g(t)=f\left(x_{1}+t\right)-f\left(x_{1}-t\right)$ ,
所以 $g^{\prime}(t)=f^{\prime}\left(x_{1}+t\right)+f^{\prime}\left(x_{1}-t\right)$
$$
\begin{aligned}
& =\frac{-3 k\left(x_{1}+t\right)^{2}}{1+x_{1}+t}\left(x_{1}+t-x_{1}\right)+\frac{-3 k\left(x_{1}-t\right)^{2}}{1+x_{1}-t}\left(x_{1}-t-x_{1}\right) \\
& =3 k t\left[\frac{\left(x_{1}-t\right)^{2}}{1+x_{1}+t}+\frac{\left(x_{1}+t\right)^{2}}{1+x_{1}-t}\right] \\
& =\frac{6 k t^{2}\left(t^{2}-x_{1}^{2}-2 x_{1}\right)}{\left(1+x_{1}\right)^{2}-t^{2}}
\end{aligned}
$$
因为 $t \in\left(0, x_{1}\right)$ ,所以 $t^{2}-x_{1}{ }^{2}-2 x_{1}<0,\left(1+x_{1}\right)^{2}-t^{2}>0$ ,
所以 $g^{\prime}(t)=\frac{6 k t^{2}\left(t^{2}-x_{1}^{2}-2 x_{1}\right)}{\left(1+x_{1}\right)^{2}-t^{2}}<0$ ,
即 $g(t)$ 在 $t \in\left(0, x_{1}\right)$ 上单调递减;
(ii)由(i)得,$g(t)$ 在 $t \in\left(0, x_{1}\right)$ 上单调递减,
所以 $g\left(x_{1}\right)<g(0)$ ,
即 $f\left(2 x_{1}\right)-f(0)<f\left(x_{1}\right)-f\left(x_{1}\right)=0, f\left(2 x_{1}\right)<0$ ,
因为 $x_{2}$ 是 $f(x)$ 的零点,所以 $f\left(x_{2}\right)=0$ ,
所以 $f\left(2 x_{1}\right)<f\left(x_{2}\right)$ ,
又因为 $x_{2}>x_{1}, 2 x_{1}>x_{1}$ ,且 $f(x)$ 在 $\left(x_{1},+\infty\right)$ 上单调递减,
所以 $2 x_{1}>x_{2}$ .