【解答】
解:(1) $\boldsymbol{a}-\boldsymbol{b}=(\cos \alpha-\cos \beta, \sin \alpha-\sin \beta)$ , $|\boldsymbol{a}-\boldsymbol{b}|^{2}=(\cos \alpha-\cos \beta)^{2}+(\sin \alpha-\sin \beta)^{2}=2-2(\cos \alpha \cdot \cos \beta+\sin \alpha \cdot \sin \beta)=2$,
所以, $\cos \alpha \cdot \cos \beta+\sin \alpha \cdot \sin \beta=0$ ,
所以, $\boldsymbol{a} \perp \boldsymbol{b}$ .
> ②$\left\{\begin{array}{ll}\cos \alpha+\cos \beta=0 & ① \\ \sin \alpha+\sin \beta=1 & ②\end{array}\right.$ ,①${ }^{2}+(2)^{2}$ 得: $\cos (\alpha-\beta)=-\frac{1}{2}$ .
所以,$\alpha-\beta=\frac{2}{3} \pi, \alpha=\frac{2}{3} \pi+\beta$ ,
带入(2)得: $\sin \left(\frac{2}{3} \pi+\beta\right)+\sin \beta=\frac{\sqrt{3}}{2} \cos \beta+\frac{1}{2} \sin \beta=\sin \left(\frac{\pi}{3}+\beta\right)=1$ ,
所以,$\frac{\pi}{3}+\beta=\frac{\pi}{2}$ .
所以,$\alpha=\frac{5 \pi}{6}, \beta=\frac{\pi}{6}$ .