如图建系,

$\overrightarrow{F E}=(1,0,0), \overrightarrow{E A^{\prime}}=\left(0, \frac{1}{2}, \frac{\sqrt{3}}{2}\right)$ ,设平面 $E F D^{\prime} A^{\prime}$ 的法向量为 $\overrightarrow{n_{1}}=\left(x_{1}, y_{1}, z_{1}\right)$
则有 $\left\{\begin{array}{c}x_{1}=0 \\ \frac{1}{2} y_{1}+\frac{\sqrt{3}}{2} z_{1}=0\end{array}\right.$ ,取 $y_{1}=-\sqrt{3}, \overrightarrow{n_{1}}=(0,-\sqrt{3}, 1)$ ;
$\overrightarrow{C B}=(1,1,0), \overrightarrow{D^{\prime} B}=\left(1, \frac{3}{2},-\frac{\sqrt{3}}{2}\right)$ ,设平面 $B C D^{\prime}$ 的法向量为 $\overrightarrow{n_{2}}=\left(x_{2}, y_{2}, z_{2}\right)$ ,则有$\left\{\begin{array}{c}x_{2}+y_{2}=0 \\ x_{1}+\frac{3}{2} y_{1}-\frac{\sqrt{3}}{2} z_{1}=0\end{array}\right.$ ,取 $y_{2}=\sqrt{3}$ ,则 $\overrightarrow{n_{2}}=(-\sqrt{3}, \sqrt{3}, 1)$
即平面 $B C D^{\prime}$ 与平面 $E F D^{\prime} A^{\prime}$ 成角 $\theta$ ,则有 $\cos \theta=\left|\frac{\overrightarrow{n_{1}} \cdot \overrightarrow{n_{2}}}{\left|\overrightarrow{n_{1}}\right| \times\left|\cdot \overrightarrow{n_{2}}\right|}\right|=\frac{\sqrt{7}}{7}$ ,故 $\sin \theta=\frac{\sqrt{42}}{7}$ .